Hexaflumuron 95% TC Content

CAS Number 86479-06-3
Chemical Name 1-(3,5-Dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl)-3-(2,6-difluorobenzoyl)urea
Molecular Weight 461.14 g/mol
Molecular Formula C₁₆H₈Cl₂F₆N₂O₃
Synonyms Hexaflumuron; DPX-7024; Gaichongsan; Liufulong
EINECS 400-110-5
Appearance White to off-white crystalline powder
Solubility Soluble in organic solvents (e.g., acetone, methanol); slightly soluble in hexane
Storage Conditions Store in a cool, dry place away from light and heat; keep container tightly closed
Category:

Parameters of Hexaflumuron :

CAS Number 86479-06-3
Chemical Name 1-(3,5-Dichloro-4-(1,1,2,2-tetrafluoroethoxy)phenyl)-3-(2,6-difluorobenzoyl)urea
Molecular Weight 461.14 g/mol
Molecular Formula C₁₆H₈Cl₂F₆N₂O₃
Synonyms Hexaflumuron; DPX-7024; Gaichongsan; Liufulong
EINECS 400-110-5
Appearance White to off-white crystalline powder
Solubility Soluble in organic solvents (e.g., acetone, methanol); slightly soluble in hexane
Storage Conditions Store in a cool, dry place away from light and heat; keep container tightly closed
Melting Point 197–199 °C
Boiling Point Decomposes before boiling
Density 1.68 g/cm³ (at 20 °C)
Vapor Pressure 0.059 × 10⁻³ Pa (at 25 °C)
Water Solubility 0.027 mg/L (at 18 °C, pH 7)
LogP (octanol-water) 5.4 (calculated)

Mechanism of Action and Insecticidal Properties

  1. Mode of Action
    As a benzoylurea insect growth regulator (IGR), hexaflumuron inhibits the activity of chitin synthase in insects, blocking the formation of cuticular chitin. This prevents larvae from molting, pupating, or emerging normally, leading to eventual death. Its unique mechanism remains effective against pests resistant to conventional insecticides (e.g., organophosphates, pyrethroids).
  2. Insecticidal Spectrum
    • Target pests: Larvae of Lepidoptera (e.g., cotton bollworm, diamondback moth, cabbage caterpillar), Coleoptera (e.g., weevils), Diptera (e.g., mosquitoes, flies), and termites.
    • Ovicidal activity: Strongly inhibits egg hatching, interrupting pest reproduction across generations.
    • Applicable crops: Cotton, cruciferous vegetables, fruit trees (apple, pear), tea, lawns, and forest trees.
  3. Key Characteristics
    • Long residual activity: A single application remains effective for 10–15 days, reducing application frequency.
    • High selectivity: Relatively safe for bees (contact/oral toxicity > 0.1 mg/bee) and natural enemies (e.g., ladybugs) but highly toxic to fish and silkworms.

 

Toxicology and Environmental Behavior

  1. Toxicity Data
    • Mammalian toxicity: Low toxicity (acute oral LD₅₀ in rats > 5000 mg/kg); mild irritation to skin and eyes; no evidence of carcinogenicity or teratogenicity.
    • Ecotoxicity:
      • Highly toxic to Daphnia (LC₅₀ (48h) = 0.0001 mg/L) and toxic to rainbow trout (LC₅₀ (96h) > 32 μg/L).
      • Low toxicity to birds (oral LD₅₀ > 2000 mg/kg) but poses long-term risks to aquatic environments.
  2. Environmental Degradation
    • Soil behavior: Half-life of 40–64 days; strongly binds to soil particles, with low leaching potential to groundwater.
    • Chemical stability: Stable under acidic conditions but readily hydrolyzes in alkaline environments (60% decomposition within 35 days at pH 9).

 

Application Scenarios and Recommendations

  1. Agricultural Control
    • Target pests:
      • Lepidopteran larvae (cotton bollworm, beet armyworm, Spodoptera litura), beetle larvae, and termites.
      • Effective against resistant populations (e.g., diamondback moth).
    • Application methods:
      • Foliar spraying: Dilute 5% emulsifiable concentrate 1000–2000 times; focus on leaf undersides and pest aggregation sites.
      • Soil treatment: For soil-dwelling pests (e.g., grubs) or termites; mix thoroughly with soil.
    • Formulation mixtures: Combinations with emamectin benzoate (e.g., 4% emamectin·hexaflumuron microemulsion) enhance quick-acting efficacy and broaden the insecticidal spectrum.
  2. Forestry and Sanitary Uses
    • Forest pests: Controls pine caterpillars and browntail moths; apply 50–75 mL of 5% emulsifiable concentrate per mu via spraying.
    • Termite control: Used in underground bait stations for long-term monitoring and elimination of termite colonies.
  3. Resistance Management
    • Avoid continuous single use; rotate with diamides (e.g., cyantraniliprole) or microbial pesticides (e.g., Bacillus thuringiensis).
    • For diamondback moth populations with resistance, combine with indoxacarb or spinetoram.

 

 

Reviews

There are no reviews yet.

Be the first to review “Hexaflumuron 95% TC Content”

Your email address will not be published. Required fields are marked *